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Eugenol synthase
Identifiers
EC no. 1.1.1.318
Databases
IntEnz IntEnz view
BRENDA BRENDA entry
ExPASy NiceZyme view
KEGG KEGG entry
MetaCyc metabolic pathway
PRIAM profile
PDB structures RCSB PDB PDBe PDBsum
Search
PMC articles
PubMed articles
NCBI proteins

Eugenol synthase ( EC 1.1.1.318, LtCES1, EGS1, EGS2) is an enzyme with systematic name eugenol:NADP+ oxidoreductase (coniferyl ester reducing). [1] [2] [3] [4] [5] [6] This enzyme catalyses the following chemical reaction: eugenol + a carboxylate + NADP+ a coniferyl ester + NADPH + H+

The enzyme acts in the reverse direction.

References

  1. ^ Koeduka T, Fridman E, Gang DR, Vassão DG, Jackson BL, Kish CM, Orlova I, Spassova SM, Lewis NG, Noel JP, Baiga TJ, Dudareva N, Pichersky E (June 2006). "Eugenol and isoeugenol, characteristic aromatic constituents of spices, are biosynthesized via reduction of a coniferyl alcohol ester". Proceedings of the National Academy of Sciences of the United States of America. 103 (26): 10128–33. doi: 10.1073/pnas.0603732103. PMC  1502517. PMID  16782809.
  2. ^ Vassão DG, Kim SJ, Milhollan JK, Eichinger D, Davin LB, Lewis NG (September 2007). "A pinoresinol-lariciresinol reductase homologue from the creosote bush (Larrea tridentata) catalyzes the efficient in vitro conversion of p-coumaryl/coniferyl alcohol esters into the allylphenols chavicol/eugenol, but not the propenylphenols p-anol/isoeugenol". Archives of Biochemistry and Biophysics. 465 (1): 209–18. doi: 10.1016/j.abb.2007.06.002. PMID  17624297.
  3. ^ Louie GV, Baiga TJ, Bowman ME, Koeduka T, Taylor JH, Spassova SM, Pichersky E, Noel JP (October 2007). "Structure and reaction mechanism of basil eugenol synthase". PLOS ONE. 2 (10): e993. Bibcode: 2007PLoSO...2..993L. doi: 10.1371/journal.pone.0000993. PMC  1991597. PMID  17912370. Open access icon
  4. ^ Koeduka T, Louie GV, Orlova I, Kish CM, Ibdah M, Wilkerson CG, Bowman ME, Baiga TJ, Noel JP, Dudareva N, Pichersky E (May 2008). "The multiple phenylpropene synthases in both Clarkia breweri and Petunia hybrida represent two distinct protein lineages". The Plant Journal. 54 (3): 362–74. doi: 10.1111/j.1365-313X.2008.03412.x. PMC  2741023. PMID  18208524.
  5. ^ Koeduka T, Baiga TJ, Noel JP, Pichersky E (January 2009). "Biosynthesis of t-anethole in anise: characterization of t-anol/isoeugenol synthase and an O-methyltransferase specific for a C7-C8 propenyl side chain". Plant Physiology. 149 (1): 384–94. doi: 10.1104/pp.108.128066. PMC  2613694. PMID  18987218.
  6. ^ Gupta AK, Schauvinhold I, Pichersky E, Schiestl FP (December 2014). "Eugenol synthase genes in floral scent variation in Gymnadenia species" (PDF). Functional & Integrative Genomics. 14 (4): 779–88. doi: 10.1007/s10142-014-0397-9. hdl: 20.500.11850/91540. PMID  25239559. S2CID  17207240.

External links