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Dioxygen monofluoride
Names
Other names
(Fluoroperoxy)radical
Fluoroperoxyl
Fluorine superoxide
Fluorodioxidanyl
Identifiers
ChemSpider
InChI=1S/FO2/c1-3-2
Key: GQRAHKRZRKCZPQ-UHFFFAOYSA-N
Properties
F O 2
Molar mass
50.996 g·mol−1
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
Dioxygen monofluoride is a binary
inorganic compound radical of
fluorine and
oxygen with the chemical formula O2 F .
[1]
[2]
[3] The compound is stable only at low temperature. This is one of many known
oxygen fluorides .
[4]
Synthesis
O2 F2 → F + O2 F
F + F → F2
F2 → 2F
F + O2 → O2 F
Physical properties
Dioxygen monofluoride is a strong
oxidizing agent , can be prepared in the coaxial reactor.
[6]
References
^ Sen, K. D. (27 August 2011).
Statistical Complexity: Applications in Electronic Structure .
Springer Science & Business Media . p. 199.
ISBN
978-90-481-3890-6 . Retrieved 18 May 2023 .
^ Campbell, G.M. (March 1990). "A kinetic study of the equilibrium between dioxygen monofluoride and dioxygen difluoride". Journal of Fluorine Chemistry . 46 (3): 357–366.
doi :
10.1016/S0022-1139(00)82921-8 .
^ Ebsworth, E. A. V.; Connor, J. A.; Turner, J. J. (6 June 2016).
The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry .
Elsevier . p. 757.
ISBN
978-1-4831-3789-6 . Retrieved 18 May 2023 .
^ Spratley, Richard D.; Turner, J. J.; Pimentel, George C. (March 1966). "Dioxygen Monofluoride: Infrared Spectrum, Vibrational Potential Function, and Bonding".
The Journal of Chemical Physics . 44 (5): 2063–2068.
doi :
10.1063/1.1726981 .
^ Ebsworth, E. A. V.; Connor, J. A.; Turner, J. J. (6 June 2016).
The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry .
Elsevier . pp. 756–757.
ISBN
978-1-4831-3789-6 . Retrieved 18 May 2023 .
^ Council, National Research; Studies, Division on Earth and Life; Resources, Commission on Geosciences, Environment and; Wastes, Molten Salt Panel of the Committee on Remediation of Buried and Tank (26 February 1997).
Evaluation of the U.S. Department of Energy's Alternatives for the Removal and Disposition of Molten Salt Reactor Experiment Fluoride Salts .
National Academies Press . p. 104.
ISBN
978-0-309-17492-3 . Retrieved 18 May 2023 . {{
cite book }}
: CS1 maint: multiple names: authors list (
link )
PF6 − , AsF6 − , SbF6 − compounds AlF6 − compounds chlorides, bromides, iodides and pseudohalogenides SiF6 2- , GeF6 2- compounds Oxyfluorides Organofluorides with transition metal, lanthanide, actinide, ammonium nitric acids bifluorides thionyl, phosphoryl, and iodosyl