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Benzil reductase ((R)-benzoin forming)
Identifiers
EC no. 1.1.1.321
Databases
IntEnz IntEnz view
BRENDA BRENDA entry
ExPASy NiceZyme view
KEGG KEGG entry
MetaCyc metabolic pathway
PRIAM profile
PDB structures RCSB PDB PDBe PDBsum
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PMC articles
PubMed articles
NCBI proteins

Benzil reductase ((R)-benzoin forming) ( EC 1.1.1.321) is an enzyme with systematic name (R)-benzoin:NADP+ oxidoreductase. [1] This enzyme catalyses the following chemical reaction

(R)- benzoin + NADP+ benzil + NADPH + H+

The bacterial enzyme ( Xanthomonas oryzae) enantioselectively reduces one of the two carbonyl groups of benzil to form optically active (R)-benzoin.

References

  1. ^ Konishi J, Ohta H, Tuchihashi G (1985). "Asymmetric reduction of benzil to benzoin catalyzed by the enzyme system of a microorganism". Chem. Lett. 14: 1111–1112. doi: 10.1246/cl.1985.1111.

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