From Wikipedia, the free encyclopedia
Phosphidogermanates are chemical compounds that have
phosphorus bound to
germanium to yield
anions. They are in the category of phosphidotetrelates and also
pnictides. They are analogous to
nitridogermanates,
phosphidoaluminates,
phosphidogallates,
phosphidoindates,
phosphidosilicates or
phosphidostannates.
They are under investigation as
infrared
non-linear optic materials
[1] and
solid-state electrolytes.
[2]
List
formula
|
MW
|
crystal
system
|
space
group
|
unit cell Å
|
volume
|
density
|
form
|
properties
|
references
|
GeP
|
|
monoclinic
|
C2/m
|
a = 15.1948 b = 3.6337 c = 9.1941 β = 101.239°
|
|
|
|
|
[3]
|
Li2GeP2
|
148.458
|
tetragonal
|
I41/acd
|
a = 12.3069 c = 19.0306 Z=32
|
2882.42
|
2.736
|
Ge4P10 supratetrahedra
|
red
|
[4]
|
LiGe3P3
|
317.751
|
orthorhombic
|
Pbam
|
a = 9.8459 b = 15.7489 c = 3.5995 Z=4
|
558.15
|
3.780
|
GeP4 and Ge(P3Ge) tetrahedra in
5 and 6-membered rings making 2D slabs
|
black
|
[4]
|
Li8GeP4
|
252
|
|
Pa3
|
a=11.80203 c=11.80203 Z=8
|
1643.88
|
2.037
|
|
|
[5]
[6]
|
Li8GeP4
|
251.99
|
cubic
|
P43n
|
a=11.77294 Z=8
|
1635.98
|
2.046
|
|
|
[5]
[6]
|
Li14GeP6
|
|
cubic
|
Fm3m
|
a=5.95667 Z=4
|
|
1.860
|
|
brown
|
[2]
[7]
|
Li10.1Ge5P
|
|
|
Pnma
|
a=10.360 b=4.3072 c=24.267 Z=4
|
1082.8
|
2.86
|
Ge5 rings
|
black; actually is a germanide phosphide
|
[8]
|
NaGe3P3
|
|
orthorhombic
|
Pmc21
|
a=3.6276 b=8.407 c=10.332 Z=2
|
315.09
|
3.517
|
Ge3P7 ring
|
red; band gap 2.06 eV; semiconductor
|
[9]
|
Na2Ge3P3
|
356.72
|
monoclinic
|
C2/m
|
a = 17.639 b = 3.6176 c = 11.354 β = 92.74° Z=4
|
723.7
|
3.274
|
|
black
|
[10]
|
Na3Ge2P3
|
307.06
|
monoclinic
|
P21/c
|
a = 7.2894 b = 14.7725 c = 7.0528 β = 106.331° Z=4
|
728.8
|
2.798
|
Ge2P6 with shared P
|
black
|
[11]
|
Na5Ge7P5
|
|
monoclinic
|
C2/m
|
a = 16.168 b = 3.6776 c = 12.924 β = 91.30° Z=2
|
768.2
|
3.343
|
|
black
|
[10]
|
Na8GeP4
|
380.4
|
cubic
|
Fd3m
|
a=13.4230 Z=8
|
2418.53
|
2.08943
|
same as Na8SnSb4
|
black; decomposes over 350°C to Na10Ge2P6;band gap 1.9 eV
|
[5]
|
Na10Ge2P6
|
|
monoclinic
|
P21/n
|
a=13.176 b =7.36.4 c=8.042 β=90.26° Z=2
|
780.29
|
2.38
|
|
beige; moisture sensitive
|
[12]
|
CuGe2P3
|
|
|
|
|
|
|
|
|
[13]
|
ZnGeP2
|
|
|
I42d
|
a=5.466 c=10.722
|
|
|
|
melt 1027°C
|
[1]
[14]
[15]
[16]
|
Ag6Ge10P12
|
1744.76
|
cubic
|
I43m
|
a=10.3111 Z=2
|
1096.3
|
5.286
|
|
air stable; silver grey; thermoelectric
|
[17]
[18]
[19]
|
CdGeP2
|
|
|
I42d
|
a=5.740 c=10.773
|
|
|
|
|
[20]
|
Cs5GeP3
|
|
orthorhombic
|
Pnma
|
a=14.31 b=5.994 c=15.618 Z=4
|
|
|
|
metallic
|
[21]
|
BaGe2P2
|
344.46
|
tetragonal
|
P42mc
|
a =7.6153 c =8.490 Z=4
|
492.3
|
4.647
|
|
light metallic grey; melt 861 °C
|
[22]
|
References
- ^
a
b Yang, He‐Di; Ran, Mao‐Yin; Wei, Wen‐Bo; Wu, Xin‐Tao; Lin, Hua; Zhu, Qi‐Long (2021-11-02).
"The Rise of Infrared Nonlinear Optical Pnictides: Advances and Outlooks". Chemistry – an Asian Journal. 16 (21): 3299–3310.
doi:
10.1002/asia.202100935.
ISSN
1861-4728.
PMID
34469055.
S2CID
237372337.
- ^
a
b Strangmueller, Stefan; Eickhoff, Henrik; Mueller, David; Klein, Wilhelm; Raudaschl-Sieber, Gabriele; Kirchhain, Holger; Sedlmeier, Christian; Baran, Volodymyr; Senyshyn, Anatolyi; Deringer, Volker L.; van Wüllen, Leo; Gasteiger, Hubert A.; Fässler, Thomas Friedrich (2020-11-23).
"Fast Lithium Ionic Conductors Li 14 SiP 6 , Li 14 GeP 6 , and Li 14 SnP 6 – Structure-Property-Relationships in the Newly Discovered Family of Lithium Phosphidotetrelates". ECS Meeting Abstracts. MA2020-02 (5): 874.
doi:
10.1149/MA2020-025874mtgabs.
ISSN
2151-2043.
S2CID
234511163.
-
^ Shen, Hailin; Ma, Zhongtao; Yang, Bingchao; Guo, Bingkun; Lyu, Yingchun; Wang, Peng; Yang, Hangsheng; Li, Qianqian; Wang, Hongtao; Liu, Zhongyuan; Nie, Anmin (September 2019).
"Sodium storage mechanism and electrochemical performance of layered GeP as anode for sodium ion batteries". Journal of Power Sources. 433: 126682.
Bibcode:
2019JPS...43326682S.
doi:
10.1016/j.jpowsour.2019.05.088.
S2CID
195416712.
- ^
a
b Eickhoff, Henrik; Sedlmeier, Christian; Klein, Wilhelm; Raudaschl‐Sieber, Gabriele; Gasteiger, Hubert A.; Fässler, Thomas F. (2020-02-14).
"Polyanionic Frameworks in the Lithium Phosphidogermanates Li 2 GeP 2 and LiGe 3 P 3 – Synthesis, Structure, and Lithium Ion Mobility". Zeitschrift für anorganische und allgemeine Chemie. 646 (3): 95–102.
doi:
10.1002/zaac.201900228.
ISSN
0044-2313.
S2CID
214226863.
- ^
a
b
c Fässler, Thomas Friedrich; Botta, Manuel; Zeitz, Sabine (2023-08-31).
"Synthesis, Structure and Physical Properties of the Most Sodium‐Rich Phosphidogermanate Na8GeP4". Zeitschrift für anorganische und allgemeine Chemie.
doi:
10.1002/zaac.202300166.
ISSN
0044-2313.
- ^
a
b Eickhoff, Henrik; Strangmüller, Stefan; Klein, Wilhelm; Kirchhain, Holger; Dietrich, Christian; Zeier, Wolfgang G.; van Wüllen, Leo; Fässler, Thomas F. (2018-09-25).
"Lithium Phosphidogermanates α- and β-Li 8 GeP 4 —A Novel Compound Class with Mixed Li + Ionic and Electronic Conductivity". Chemistry of Materials. 30 (18): 6440–6448.
doi:
10.1021/acs.chemmater.8b02759.
ISSN
0897-4756.
S2CID
106211828.
-
^ Strangmüller, Stefan; Eickhoff, Henrik; Raudaschl-Sieber, Gabriele; Kirchhain, Holger; Sedlmeier, Christian; van Wüllen, Leo; Gasteiger, Hubert A.; Fässler, Thomas F. (2020-08-25).
"Modifying the Properties of Fast Lithium-Ion Conductors—The Lithium Phosphidotetrelates Li 14 SiP 6 , Li 14 GeP 6 , and Li 14 SnP 6". Chemistry of Materials. 32 (16): 6925–6934.
doi:
10.1021/acs.chemmater.0c02052.
ISSN
0897-4756.
S2CID
225445668.
-
^ Eickhoff, H.; Klein, W.; Toffoletti, L.; Raudaschl‐Sieber, G.; Fässler, T. F. (2022-05-25).
"Planar Si 5 and Ge 5 Pentagons beside Isolated Phosphide Anions in Lithium Phosphide Tetrelides Li 10+x Si 5 P and Li 10+x Ge 5 P". Zeitschrift für anorganische und allgemeine Chemie. 648 (10).
doi:
10.1002/zaac.202100376.
ISSN
0044-2313.
S2CID
246183043.
-
^ Feng, Kai; Yin, Wenlong; He, Ran; Lin, Zheshuai; Jin, Shifeng; Yao, Jiyong; Fu, Peizhen; Wu, Yicheng (2012).
"NaGe 3 P 3 : a new ternary germanium phosphide featuring an unusual [Ge 3 P 7 ] ring". Dalton Trans. 41 (2): 484–489.
doi:
10.1039/C1DT11345C.
ISSN
1477-9226.
PMID
22042509.
- ^
a
b Eickhoff, Henrik; Hlukhyy, Viktor; Fässler, Thomas F. (2020-11-30).
"Na 2 Ge 3 P 3 and Na 5 Ge 7 P 5 Comprising Heteroatomic Polyanions Mimicking the Structure of Fibrous Red Phosphorus". Zeitschrift für anorganische und allgemeine Chemie. 646 (22): 1834–1838.
doi:
10.1002/zaac.202000316.
ISSN
0044-2313.
S2CID
225006755.
-
^ Botta, Manuel; Zeitz, Sabine; Klein, Wilhelm; Raudaschl-Sieber, Gabriele; Fässler, Thomas F. (2024-04-19).
"Na 3 Ge 2 P 3 : A Zintl Phase Featuring [P 3 Ge–GeP 3 ] Dimers as Building Blocks". Inorganic Chemistry.
doi:
10.1021/acs.inorgchem.4c00287.
ISSN
0020-1669.
-
^ Roesky, Herbert W.; Noltemeyer, Mathias; Sheldrick, George M. (1985-07-01).
"Synthese und Struktur des Trifluoracetyldicyanomethanids". Zeitschrift für Naturforschung B. 40 (7): 883–890.
doi:
10.1515/znb-1985-0706.
ISSN
1865-7117.
S2CID
95632691.
-
^ Hailing, Tu; Saunders, G.A.; Omar, M.S.; Pamplin, B.R. (January 1984).
"The elastic behaviour of the ternary zincblende structure semiconductor CuGe2P3". Journal of Physics and Chemistry of Solids. 45 (2): 163–172.
Bibcode:
1984JPCS...45..163H.
doi:
10.1016/0022-3697(84)90115-X.
-
^ Boyd, G. D.; Buehler, E.; Storz, F. G. (1971-04-01).
"LINEAR AND NONLINEAR OPTICAL PROPERTIES OF ZnGeP2 AND CdSe". Applied Physics Letters. 18 (7): 301–304.
Bibcode:
1971ApPhL..18..301B.
doi:
10.1063/1.1653673.
ISSN
0003-6951.
-
^ Carnio, B. N.; Zhang, M.; Zawilski, K. T.; Schunemann, P. G.; Moutanabbir, O.; Elezzabi, A. Y. (19 May 2023).
"Intra-pulse difference frequency generation in ZnGeP2 for high-frequency terahertz radiation generation". Scientific Reports. 13 (1): 8161.
Bibcode:
2023NatSR..13.8161C.
doi:
10.1038/s41598-023-35131-6.
PMC
10199089.
PMID
37208445.
-
^ Buehler, E.; Wernick, J. H.; Wiley, J. D. (August 1973).
"The ZnP2-Ge system and growth of single crystals of ZnGeP2". Journal of Electronic Materials. 2 (3): 445–454.
Bibcode:
1973JEMat...2..445B.
doi:
10.1007/BF02660148.
ISSN
0361-5235.
S2CID
94941316.
-
^ Nowak, E.; Neumann, H.; Omar, M. S. (January 1988).
"Heat capacity of Ag6Ge10p12 from 180 to 550 K". Crystal Research and Technology. 23 (1): 103–106.
doi:
10.1002/crat.2170230114.
-
^ Nuss, Jürgen; Wedig, Ulrich; Xie, Wenjie; Yordanov, Petar; Bruin, Jan; Hübner, Ralph; Weidenkaff, Anke; Takagi, Hidenori (2017-08-22).
"Phosphide–Tetrahedrite Ag 6 Ge 10 P 12 : Thermoelectric Performance of a Long-Forgotten Silver-Cluster Compound". Chemistry of Materials. 29 (16): 6956–6965.
doi:
10.1021/acs.chemmater.7b02474.
ISSN
0897-4756.
-
^ Namiki, H.; Kobayashi, M.; Nagata, K.; Saito, Y.; Tachibana, N.; Ota, Y. (June 2022).
"Relationship between the density of states effective mass and carrier concentration of thermoelectric phosphide Ag6Ge10P12 with strong mechanical robustness". Materials Today Sustainability. 18: 100116.
doi:
10.1016/j.mtsust.2022.100116.
S2CID
246977030.
-
^ Masumoto, K.; Isomura, S.; Goto, W. (November 1966).
"The preparation and properties of ZnSiAs2, ZnGeP2 and CdGeP2 semiconducting compounds". Journal of Physics and Chemistry of Solids. 27 (11–12): 1939–1947.
Bibcode:
1966JPCS...27.1939M.
doi:
10.1016/0022-3697(66)90124-7.
-
^ Eisenmann, Brigitte; Klein, Jürgen; Somer, Mehmet (January 1990).
"Anions Isosteric with CO32− in Cs5SiP3, Cs5SiAs3, Cs5GeP3, and Cs5GeAs3". Angewandte Chemie International Edition in English. 29 (1): 87–88.
doi:
10.1002/anie.199000871.
ISSN
0570-0833.
-
^ Chen, Jindong; Lin, Chensheng; Peng, Guang; Xu, Feng; Luo, Min; Yang, Shunda; Shi, Shuangshuang; Sun, Yingshuang; Yan, Tao; Li, Bingxuan; Ye, Ning (2019-12-24).
"BaGe 2 Pn 2 (Pn = P, As): Two Congruent-Melting Non-chalcopyrite Pnictides as Mid- and Far-Infrared Nonlinear Optical Materials Exhibiting Large Second Harmonic Generation Effects". Chemistry of Materials. 31 (24): 10170–10177.
doi:
10.1021/acs.chemmater.9b03863.
ISSN
0897-4756.
S2CID
212863749.