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Petalite
Petalite from Minas Gerais State, Brazil (size: 3x4 cm)
General
Category Tektosilicate
Formula
(repeating unit)
LiAlSi4O10
IMA symbolPtl [1]
Strunz classification9.EF.05
Crystal system Monoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP2/a
Unit cella = 11.737 Å,
b = 5.171 Å,
c = 7.63 Å;
β = 112.54°; Z = 2
Identification
ColorColorless, grey, yellow, pink, to white
Crystal habitTabular prismatic crystals and columnar masses
TwinningCommon on {001}, lamellar
CleavagePerfect on {001}, poor on {201} with 38.5° angle between the two
FractureSubconchoidal
TenacityBrittle
Mohs scale hardness6–6.5
LusterVitreous, pearly on cleavages
StreakColorless
DiaphaneityTransparent to translucent
Specific gravity2.4
Optical propertiesBiaxial (+)
Refractive indexnα = 1.504, nβ = 1.510, nγ = 1.516
Birefringenceδ = 0.012
2V angle82–84° measured
Melting point1350 °C [2]
Fusibility5
SolubilityInsoluble
References [3] [4] [5] [6]

Petalite, also known as castorite, is a lithium aluminum tektosilicate mineral Li Al Si4 O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component. [7] Petalite (and secondary spodumene formed from it) is lower in iron than primary spodumene, making it a more useful source of lithium in, e.g., the production of glass. The colorless varieties are often used as gemstones. [ citation needed]

Discovery and occurrence

Petalite from Paprok, Nuristan Province, Afghanistan (size: 7.3 × 2.9 × 2.4 cm)

Petalite was discovered in 1800, by Brazilian naturalist and statesman Jose Bonifacio de Andrada e Silva. Type locality: Utö Island, Haninge, Stockholm, Sweden. The name is derived from the Greek word petalon, which means leaf, alluding to its perfect cleavage. [5] [8] [9]

Economic deposits of petalite are found near Kalgoorlie, Western Australia; Aracuai, Minas Gerais, Brazil; Karibib, Namibia; Manitoba, Canada; and Bikita, Zimbabwe.

The first important economic application for petalite was as a raw material for the glass-ceramic cooking ware CorningWare.[ citation needed] It has been used as a raw material for ceramic glazes.

References

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode: 2021MinM...85..291W. doi: 10.1180/mgm.2021.43. S2CID  235729616.
  2. ^ "Petalite". Digital Fire. Retrieved 23 October 2011.
  3. ^ Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Petalite" (PDF). Handbook of Mineralogy. Mineral Data Publishing. Retrieved 14 March 2022.
  4. ^ Webmineral
  5. ^ a b Petalite, Mindat.org
  6. ^ *Hurlbut, Cornelius S. and Klein, Cornelis, 1985, Manual of Mineralogy, Wiley, 20th ed., pp. 459–460 ISBN  0-471-80580-7
  7. ^ Deer, W. A. (2004). Framework silicates: silica minerals, feldspathoids and the zeolites (2. ed.). London: Geological Soc. p. 296. ISBN  978-1-86239-144-4.
  8. ^ D'Andraba (1800). "Des caractères et des propriétés de plusieurs nouveaux minérauxde Suède et de Norwège , avec quelques observations chimiques faites sur ces substances". Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts. 51: 239.
  9. ^ Sowerby, James (1811). Exotic mineralogy: Or, Coloured figures of foreign minerals: As a supplement to British mineralogy.

External links