Nickel(II) acetate is the name for the
coordination compounds with the formula Ni(CH3CO2)2·x H2O where x can be 0, 2, and 4. The green tetrahydrate Ni(CH3CO2)2·4 H2O is most common. It is used for
electroplating.
Synthesis and structure
The compound can be prepared by treating nickel or
nickel(II) carbonate with acetic acid:
The green tetrahydrate has been shown by
X-ray crystallography to adopt an octahedral structure, the central nickel centre being coordinated by four water molecules and two acetate
ligands.[5] It may be dehydrated in vacuo, by reaction with
acetic anhydride[6] or by heat.[7]
Safety
Nickel salts are carcinogenic and irritate the skin.
References
^M. A. Mohamed, S. A. Halawy, M. M. Ebrahim: "Non-isothermal decomposition of nickel acetate tetrahydrate", in: Journal of Analytical and Applied Pyrolysis, 1993, 27 (2), S. 109–110.
doi:
10.1016/0165-2370(93)80002-H.
^Van Niekerk, J. N.; Schoening, F. R. L. (1953). "The crystal structures of nickel acetate, Ni(CH3COO)2·4H2O, and cobalt acetate, Co(CH3COO)2·4H2O". Acta Crystallogr.6 (7): 609–612.
doi:
10.1107/S0365110X5300171X.
^Tappmeyer, W. P.; Davidson, Arthur W. (1963). "Cobalt and Nickel Acetates in Anhydrous Acetic Acid". Inorg. Chem.2 (4): 823–825.
doi:
10.1021/ic50008a039.