The bulk of meteoric iron consists of
taenite and
kamacite. Taenite is a face-centered cubic and kamacite a body-centered cubic iron-nickel
alloy.
Meteoric iron can be distinguished from
telluric iron by its microstructure and perhaps by its chemical composition also, since meteoritic iron contains more nickel and less carbon.[2]
Trace amounts of
gallium and
germanium in meteoric iron can be used to distinguish different meteorite types. The meteoric iron in
stony iron meteorites is identical to the "gallium-germanium group" of the
iron meteorites.[3]
Meteoric iron forms a few different structures that can be seen by
etching or in
thin sections of meteorites. The
Widmanstätten pattern forms when meteoric iron cools and
kamacite is
exsolved from
taenite in the form of lamellas.[5]Plessite is a more fine-grained intergrowth of the two minerals in between the lamella of the Widmanstätten pattern.[6]Neumann lines are fine lines running through
kamacite crystals that form through impact-related deformation.[7]
Before the advent of iron
smelting, meteoric iron was the only source of iron metal apart from minor amounts of
telluric iron. Meteoric iron was already used before the beginning of the
Iron Age to make cultural objects, tools and weapons.[8]
Many examples of iron working from the
Bronze Age have been confirmed to be meteoritic in origin.[9]
In ancient Egypt an iron metal bead was found in a graveyard near
Gerzeh that contained 7.5% Ni.[10][11] Dated to around 3200 BC,
geochemical analysis of the Gerzeh iron beads, based on the ratio of nickel to iron and
cobalt, confirms that the iron was meteoritic in origin.[9]
Dated to around 2500 BC, an iron dagger from
Alaca Höyük was confirmed to be meteoritic in origin through geochemical analysis.[9]
Dated to around 2300 BC, an iron pendant from
Umm el-Marra in Syria was confirmed to be meteoritic in origin through geochemical analysis.[9]
Dated to around 1400 BC, an iron axe from
Ugarit in Syria was found to be meteoritic in origin.[9]
Dated to around 1400 BC, several iron axes from the
Shang Dynasty in China were also confirmed to be meteoritic in origin.[9]
Dated to around 1350 BC, an iron dagger, bracelet and headrest from the tomb of
Tutankhamun were confirmed to be meteoritic in origin.[9] The
Tutankhamun dagger consists of similar proportions of metals (
iron,
nickel and
cobalt) to a meteorite discovered in the area, deposited by an ancient meteor shower.[12][13][14]
Dated to around 900 BC, an iron
arrowhead from
Mörigen in Switzerland was confirmed to be meteoritic in origin.[15]
Fragments from the
Gibeon meteorite were used for centuries by the
Nama people of Namibia.
Asia
There are reports of the use of meteorites for manufacture of various items in Tibet (see
Thokcha).
The
Iron Man, a purported Tibetan Buddhist statue of
Vaiśravaṇa, was likely carved from an ataxite meteorite.[19] It has been speculated that it may be made from a fragment of the
Chinga meteorite.[20][21]
Even after the invention of
smelting, meteoric iron was sometimes used where this technology was not available or metal was scarce. A piece of the
Cranbourne meteorite was made into a horseshoe around 1854.[22]
Today meteoritic iron is used in niche jewellery and knife production, but most of it is used for research, educational or
collecting purposes.
Atmospheric phenomena
Meteoric iron also has an effect on the Earth's atmosphere. When meteorites descend through the atmosphere, outer parts are
ablated. Meteoric ablation is the source of many elements in the upper atmosphere. When meteoric iron is ablated, it forms a free iron atom that can react with
ozone (O3) to form
FeO. This FeO may be the source of the orange spectrographic bands in the spectrum of the upper atmosphere.[23]
^Lovering, John F.; Nichiporuk, Walter; Chodos, Arthur; Brown, Harrison (31 December 1956). "The distribution of gallium, germanium, cobalt, chromium, and copper in iron and stony-iron meteorites in relation to nickel content and structure". Geochimica et Cosmochimica Acta. 11 (4): 263–278.
Bibcode:
1957GeCoA..11..263L.
doi:
10.1016/0016-7037(57)90099-6.
^Waldbaum, J. C. and James D. Muhly; The first archaeological appearance of iron and the transition to the iron age chapter in The coming of the age of iron, Theodore A. Wertme. ed., Yale University Press, 1980,
ISBN978-0300024258
^Iron and steel in ancient times by Vagn Fabritius Buchwald - Det Kongelige Danske Videnskabernes Selskab 2005
^T. A. Rickard (1941). "The Use of Meteoric Iron". Journal of the Royal Anthropological Institute. 71 (1/2): 55–66.
doi:
10.2307/2844401.
JSTOR2844401.
^Evans, W. F. J.; Gattinger, R. L.; Slanger, T. G.; Saran, D. V.; et al. (20 November 2010). "Discovery of the FeO orange bands in the terrestrial night airglow spectrum obtained with OSIRIS on the Odin spacecraft". Geophysical Research Letters. 37 (22): L22105.
Bibcode:
2010GeoRL..3722105E.
doi:
10.1029/2010GL045310.
S2CID130887275.