Alloy of nickel and iron with low coefficient of thermal expansion
Invar, also known generically as FeNi36 (64FeNi in the US), is a
nickel–
ironalloy notable for its uniquely low
coefficient of thermal expansion (CTE or α). The name Invar comes from the word invariable, referring to its relative lack of expansion or contraction with temperature changes,[1] and is a registered trademark of
ArcelorMittal.[2]
The discovery of the alloy was made in 1895 by Swiss physicist
Charles Édouard Guillaume for which he received the
Nobel Prize in Physics in 1920. It enabled improvements in scientific instruments.[3]
Properties
Like other nickel/iron compositions, Invar is a
solid solution; that is, it is a
single-phasealloy. In one commercial version it consists of approximately 36% nickel and 64% iron.[4] The invar range was described by Westinghouse scientists in 1961 as "30–45 atom per cent nickel".[5]
Common grades of Invar have a coefficient of thermal expansion (denoted α, and measured between 20 °C and 100 °C) of about 1.2 × 10−6K−1 (1.2
ppm/°C), while ordinary steels have values of around 11–15 ppm/°C.[citation needed] Extra-pure grades (<0.1%
Co) can readily produce values as low as 0.62–0.65 ppm/°C.[citation needed] Some formulations display
negative thermal expansion (NTE) characteristics.[citation needed] Though it displays high dimensional stability over a range of temperatures, it does have a propensity to
creep.[6][7]
Applications
Invar is used where high dimensional stability is required, such as precision instruments, clocks, seismic creep gauges, color-television tubes'
shadow-mask frames,[8] valves in engines and large aerostructure molds.[9]
One of its first applications was in watch
balance wheels and
pendulum rods for precision
regulator clocks. At the time it was invented, the
pendulum clock was the world's most precise timekeeper, and the limit to timekeeping accuracy was due to thermal variations in length of clock pendulums. The
Riefler regulator clock developed in 1898 by Clemens Riefler, the first clock to use an Invar pendulum, had an accuracy of 10 milliseconds per day, and served as the primary time standard in
naval observatories and for national time services until the 1930s.
In
land surveying, when first-order (high-precision) elevation
leveling is to be performed, the
level staff (leveling rod) used is made of Invar, instead of wood, fiberglass, or other metals.[10][11] Invar struts were used in some pistons to limit their thermal expansion inside their cylinders.[12] In the manufacture of large
composite material structures for
aerospacecarbon fibrelayup molds, Invar is used to facilitate the manufacture of parts to extremely tight tolerances.[13]
In the astronomical field, Invar is used as the structural components that support dimension-sensitive optics of astronomical telescopes.[14] Superior dimensional stability of Invar allows the astronomical telescopes to significantly improve the observation precision and accuracy.
Variations
There are variations of the original Invar material that have slightly different coefficient of thermal expansion such as:
FeNi42 (for example NILO alloy 42), which has a nickel content of 42% and α ≈ 5.3 ppm/°C, matching that of
silicon, is widely used as lead frame material for integrated circuits, etc.[citation needed]
FeNiCo alloys—named Kovar or Dilver P—that have the same expansion behaviour (~5 ppm/°C) and form strong bonds with molten
borosilicate glass, and because of that are used for
glass-to-metal seals, and to support optical parts in a wide range of temperatures and applications, such as
satellites.[citation needed]
Explanation of anomalous properties
A detailed explanation of Invar's anomalously low CTE has proven elusive for physicists.
All the iron-rich face-centered cubic Fe–Ni alloys show Invar anomalies in their measured thermal and magnetic properties that evolve continuously in intensity with varying alloy composition. Scientists had once proposed that Invar's behavior was a direct consequence of a high-magnetic-moment to low-magnetic-moment transition occurring in the face centered cubic Fe–Ni series (and that gives rise to the mineral
antitaenite); however, this theory was proven incorrect.[15] Instead, it appears that the low-moment/high-moment transition is preceded by a high-magnetic-moment
frustrated ferromagnetic state in which the Fe–Fe magnetic exchange bonds have a large magneto-volume effect of the right sign and magnitude to create the observed thermal expansion anomaly.[16]
Wang et al. considered the statistical mixture between the fully ferromagnetic (FM) configuration and the spin-flipping configurations (SFCs) in Fe 3Pt with the free energies of FM and SFCs predicted from first-principles calculations and were able to predict the temperature ranges of negative thermal expansion under various pressures.[17] It was shown that all individual FM and SFCs have positive thermal expansion, and the negative thermal expansion originates from the increasing populations of SFCs with smaller volumes than that of FM.[18]
See also
Constantan and
Manganin, alloys with relatively constant electrical resistivity
Elinvar, alloy with relatively constant elasticity over a range of temperatures
Sitall and
Zerodur, ceramic materials with a relatively low thermal expansion
^"The Nobel Prize in Physics 1920". nobelprize.org. The Nobel Foundation. Retrieved 20 March 2011. The Nobel Prize in Physics 1920 was awarded to Charles Edouard Guillaume "in recognition of the service he has rendered to precision measurements in Physics by his discovery of anomalies in nickel steel alloys".
^Ananthanarayanan, N. I.; Peavler, R. J. (1961). "A New Reversible Solid-State Transformation in Iron–Nickel Alloys in the Invar Range of Compositions". Nature. 192 (4806): 962–963.
Bibcode:
1961Natur.192..962A.
doi:
10.1038/192962a0.
S2CID4277440.
^Wang, Y., Shang, S. L., Zhang, H., Chen, L.-Q., & Liu, Z.-K. (2010). Thermodynamic fluctuations in magnetic states: Fe 3 Pt as a prototype. Philosophical Magazine Letters, 90(12), 851–859.
https://doi.org/10.1080/09500839.2010.508446