From Wikipedia, the free encyclopedia
Hydrotelluride
Names
Other names
tellanide
Identifiers
ChEBI
ChemSpider
1407875
Key: VTLHPSMQDDEFRU-UHFFFAOYSA-M
Properties
H Te −
Molar mass
128.61 g·mol−1
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
A hydrotelluride or tellanide is an
ion or a
chemical compound containing the [HTe]− anion which has a
hydrogen atom connected to a
tellurium atom. HTe is a
pseudohalogen . Organic compounds containing the -TeH group are called
tellurols . "Tellanide" is the IUPAC name from the Red Book, but hydrogen(tellanide)(1−) is also listed. "Tellanido" as a ligand is not named, however ditellanido is used for HTeTe− .
[1]
Hydrotellurides are usually unstable at room temperature.
[2]
List
formula
system
space group
unit cell Å
volume
density
comment
reference
ammonium hydrotelluride
NH4 TeH
at 25°C pressure = 22.7 mmHg, decomposing to H3 N and H2 Te then to Te and H2
[3]
ethylmethylimidazolinium hydrotelluride
[(C2 H5 )(CH3 )C3 N2 H2 + TeH−
[2]
N -butyl-N -methylpyrollidinium hydrotelluride
[(C4 H9 )(CH3 )C4 NH8 + TeH−
decompose at room temperature over a fortnight;
decompose 116°C
[2]
sodium hydrotelluride
NaTeH
[4]
tri-n-butyl-methylphosphonium hydrotelluride
[(C4 H9 )3 (CH3 )P]+ TeH−
red; decompose 163°C
[2]
tetraphenylphosphonium hydrotelluride
Ph4 PTeH
[5]
[(C5 H5 )Co]2 (μ-P(CH3 )2 )2 (μ-TeH)•PF6
red-brown
[6]
Na[(CO)5 Cr(TeH)]
[7]
[8]
[(Ph3 P)2 N]+ [(CO)5 Cr(TeH)]−
[8]
[(Ph3 P)2 N]+ [(CO)5 Cr(TeH)Cr(CO)5 −
[7]
[8]
[CpCr(CO)3 2 (μ-TeH)
[7]
[(CO)4 Mn(TeH)]2
[7]
[9]
Cp*=C5 Me5
Cp*2 Zr(TeH){η1 -OC(Ph)=CH2 }
[10]
(t -BuC5 H4 )2 Nb(η2 -Te2 )H
dark orange
[11]
(η-C5 H4 Me)Ru(PPh3 )2 (TeH)
[12]
(CH2 CH2 PPh2 )3 PRhTeH
hexagonal
P 63
a=13.542 c=12.346 Z=2
cherry red; decomposed by light
[13]
[5]
(CH2 CH2 PPh2 )3 PRh(TeH)(H)CF3 SO3
[13]
(MeCp)2 Ta(TeH)CO
[14]
(MeCp)2 Ta(TeH) (η 2 -COTe)
[14]
Na[(CO)5 W(TeH)]
[7]
[8]
Ph4 As[(CO)5 W(TeH)]
[8]
Ph4 As[(CO)5 W(TeH)W(CO)5 ]
[7]
[8]
Cp*Re(CO)2 (H)(TeH)
monoclinic
P 21 /m
a=7.467 b=13.208 c=7.570 β=99.48° Z=2
2.287
red-brown
[15]
[16]
[7]
(Ad ArO)3 N3− = tris(2-hydroxy-3-adamantyl-5-methylbenzyl)amine)
[((Ad ArO)3 N)U(CH3 OC2 H4 OCH3 )(TeH)]
stable to 80°C; U–Te bond length 3.122 Å
[17]
{((Ad ArO)3 N)U}2 (μ-TeH)2
[17]
References
^ . For the group -HTe or radical HTe• the term tellanyl is used.
Nomenclature of Inorganic Chemistry IUPAC Recommendations 2005 (PDF) . p. 304.
^
a
b
c
d Finger, Lars H.; Sundermeyer, Jörg (2016-03-14).
"Halide-Free Synthesis of Hydrochalcogenide Ionic Liquids of the Type [Cation][HE] (E=S, Se, Te)" . Chemistry – A European Journal . 22 (12): 4218–4230.
doi :
10.1002/chem.201504577 .
ISSN
0947-6539 .
PMID
26879604 .
^ Mikus, F. F.; Carlyon, S. J. (May 1950).
"The Equilibrium between Ammonia and Hydrogen Telluride 1" . Journal of the American Chemical Society . 72 (5): 2295–2296.
doi :
10.1021/ja01161a522 .
ISSN
0002-7863 .
^ "The Structure of Yttrium Hydride Telluride YHTe from Single-Crystal X-Ray Diffraction Data". Joint Polish-German Crystallographic Meeting, February 24–27, 2020, Wrocław, Poland : 64–65. 24 February 2020.
doi :
10.1515/9783110692914-002 .
^
a
b Roof, Lisa C.; Kolis, Joseph W. (1993-05-01).
"New developments in the coordination chemistry of inorganic selenide and telluride ligands" . Chemical Reviews . 93 (3): 1037–1080.
doi :
10.1021/cr00019a010 .
ISSN
0009-2665 .
^ Hofmann, Werner; Werner, Helmut (December 1981).
"Electrophilic Addition of a Sulfur, Selenium, and Tellurium Atom as well as of an SO 2 Molecule to a Metal-Metal Bond" . Angewandte Chemie International Edition in English . 20 (12): 1014–1016.
doi :
10.1002/anie.198110142 .
ISSN
0570-0833 .
^
a
b
c
d
e
f
g Howard, William A.; Parkin, Gerard (January 1994).
"Terminal oxo, sulfido, selenido, and tellurido complexes of zirconium, (.eta.5-C5Me4R)2Zr(E)(NC5H5): comparison of terminal Zr-E single and Zr:E double-bond lengths" . Journal of the American Chemical Society . 116 (2): 606–615.
doi :
10.1021/ja00081a022 .
ISSN
0002-7863 .
^
a
b
c
d
e
f Hausmann, Heinz; Höfler, Mathias; Kruck, Thomas; Zimmermann, Heinz Willi (March 1981).
"Chalkogenide als Komplexliganden, I. Carbonyl-Hydrogenchalkogenid-Komplexe von Chrom, Molybdän und Wolfram" . Chemische Berichte . 114 (3): 975–981.
doi :
10.1002/cber.19811140315 .
ISSN
0009-2940 .
^ Küllmer, Volker; Vahrenkamp, Heinrich (January 1977).
"Selen- und Tellur-verbrückte Carbonylkomplexe des Mangans und Rheniums" . Chemische Berichte . 110 (1): 228–236.
doi :
10.1002/cber.19771100122 .
ISSN
0009-2940 .
^ Howard, William A.; Parkin, Gerard (January 1994).
"Terminal oxo, sulfido, selenido, and tellurido complexes of zirconium, (.eta.5-C5Me4R)2Zr(E)(NC5H5): comparison of terminal Zr-E single and Zr:E double-bond lengths" . Journal of the American Chemical Society . 116 (2): 606–615.
doi :
10.1021/ja00081a022 .
ISSN
0002-7863 .
^ Ebner, Alexander; Meier, Walter; Mugnier, Yves; Wachter, Joachim (July 2007).
"Investigation into the reaction of (t-BuC5H4)2Nb(η2-Te2)H with CH3Li: Hydride abstraction versus telluride methylation" . Inorganica Chimica Acta . 360 (10): 3330–3334.
doi :
10.1016/j.ica.2007.03.060 .
^ Schriver, D. F.; Bruce, M. I. (2002-09-10).
Comprehensive Organometallic Chemistry II, Volume 7: Iron, Ruthenium and Osmium: A Review of the Literature 1982-1994 . Elsevier. p. 883.
ISBN
978-0-08-096396-9 .
^
a
b Di Vaira, Massimo; Peruzzini, Maurizio; Stoppioni, Piero (March 1991).
"Hydrochalcogenide and hydride hydrochalcogenide derivatives of rhodium" . Inorganic Chemistry . 30 (5): 1001–1007.
doi :
10.1021/ic00005a024 .
ISSN
0020-1669 .
^
a
b Winkler, Uwe; Khan, Masood A.; Nicholas, Kenneth M. (August 1998).
"Atom addition and insertion reactions of (MeCp)2Ta(H)CO with sulfur, tellurium, carbonyl sulfide and carbon disulfide" . Inorganic Chemistry Communications . 1 (8): 317–319.
doi :
10.1016/S1387-7003(98)00085-9 .
^ Herrmann, Wolfgang A.; Hecht, Christian; Herdtweck, Eberhardt; Kneuper, Heinz-Josef (February 1987).
"Oxidative Addition of Hydrogen Telluride to Organometallic Fragments" . Angewandte Chemie International Edition in English . 26 (2): 132–134.
doi :
10.1002/anie.198701321 .
ISSN
0570-0833 .
^ Fehlner, Thomas P. (1992), Fehlner, Thomas P. (ed.),
"Main Group Fragments as Ligands to Transition Metals" , Inorganometallic Chemistry , Boston, MA: Springer US, pp. 13–71,
doi :
10.1007/978-1-4899-2459-9_2 ,
ISBN
978-1-4899-2461-2 , retrieved 2024-05-23
^
a
b Franke, Sebastian M.; Rosenzweig, Michael W.; Heinemann, Frank W.; Meyer, Karsten (2015).
"Reactivity of uranium( iii ) with H 2 E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium( iv ) hydrochalcogenido complexes" . Chemical Science . 6 (1): 275–282.
doi :
10.1039/C4SC02602K .
ISSN
2041-6520 .
PMC
5811169 .
PMID
29560170 .
Salts and covalent derivatives of the
telluride ion