From Wikipedia, the free encyclopedia
Ferrario–Ackermann reaction
Named after
M. E. Ferrario Fritz Ackermann
Reaction type
Ring forming reaction
In
organic chemistry , the Ferrario–Ackermann reaction or simply the Ferrario reaction is a
name reaction that allow for the generation of phenoxanthiine from diphenyl ether and
sulfur in the presence of
aluminum chloride catalyst.
[1]
[2]
[3]
[4]
[5]
[6]
References
^ Ferrario, E. (January 1911).
"Preparation of phenoxathiin from diphenyl ether and sulfur" . Bulletin de la Société Chimique de France . 9 (4): 536–537.
^
Germany 234743 , Fritz Ackermann, "Verfahren zur Darstellung von Phenoxthin und dessen Derivaten", published 20 May 1911
^ Deasy, Clara L. (1 April 1943). "The Chemistry of Phenoxathiin and its Derivatives". Chemical Reviews . 32 (2): 173–194.
doi :
10.1021/cr60102a001 .
^ Suter, C. M.; Maxwell, Charles E.
"Phenoxthin [Phenoxathiin]" .
Organic Syntheses . 18 : 64.
doi :
10.15227/orgsyn.018.0064 ; Collected Volumes , vol. 2, p. 485 .
^ Al-Araji, Suad M.; Mohamad, Ayad Ahmed (2 June 201).
"Synthesis of New Pyrazoline - Phenoxathiin Derivatives" . Baghdad Science Journal . 10 (2): 405–419.
doi :
10.21123/bsj.2013.10.2.405-419 .
^ Suter, C. M.; Green, Frank O. (1 December 1937). "Phenoxthin. II. Extension of the Ferrario Reaction". Journal of the American Chemical Society . 59 (12): 2578–2580.
doi :
10.1021/ja01291a030 .