The carbonate oxalates are mixed anion compounds that contain both carbonate (CO3) and oxalate (C2O4) anions. Most compounds incorporate large trivalent metal ions, such as the rare earth elements. Some carbonate oxalate compounds of variable composition are formed by heating oxalates. [1]
One method to form carbonate oxalates is to heat a metal salt with ascorbic acid, which decomposes to oxalate and carbonate and combines with the metal. [2]
When heated, oxalate carbonates decompose to carbon monoxide and carbonates, which form oxides at higher temperatures. [2]
formula | name | formula weight | crystal form | space group | unit cell Å | volume Å3 | density | properties | references |
---|---|---|---|---|---|---|---|---|---|
Sc | [3] | ||||||||
K4Ti2O2(C2O4)3·CO3 | [4] | ||||||||
[Co*(C2O4)(CO3)]2− | anionic complex | [5] | |||||||
[CoIII(CO3)(C2O4)(NH3)2]- | anionic complex | [6] | |||||||
CaCu3(TiO)4(C2O4)5(CO3)3·CO2 | [7] | ||||||||
Sr[TiO(C2O4)CO3] | |||||||||
[Y(H2O)]2(C2O4)(CO3)2 | yttrium oxalate carbonate | 421.876 | orthorhombic | C2221 | a = 7.8177, b = 14.943, c = 9.4845, Z = 4 | 1108.0 | 2.526 | [8] | |
Ba[ZrO(C2O4)(CO3)] | [9] | ||||||||
[Ce(H2O)]2[(C2O4)2(CO3)]·2.5H2O | triclinic | P1_ | a 6.329 b 8.743 c 13.000, α 105.61° β 90.55° γ 105.10° | [10] | |||||
Pr4(C2O4)4(CO3)2]·3H2O | catena(bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-praseodymium hydrate) | triclinic | P1_ | a 6.298 b 8.673 c 12.970, α 105.42° β 90.55° γ 105.01° | [11] | ||||
Pr2(C2O4)(CO3)2 | [12] | ||||||||
Nd4(C2O4)4(CO3)2]·3H2O | catena-[bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-neodymium hydrate] | triclinic | P1_ | a 6.273(6)Å b 8.616(7)Å c 12.928(9)Å, α 105.50(6)° β 90.52(7)° γ 105.00(6)° | [11] | ||||
(NH4)2[Nd2(CO3)(C2O4)3(H2O)]·H2O | diammonium aqua—carbonato-tri—oxalato-dineodymium(III) hydrate | triclinic | P1_ | a=8.706 b=9.530 c=10.327 α = 73.35° β = 86.90° γ = 80.50° Z=2 | 809.69 | 2.808 | [13] | ||
Eu4(C2O4)4(CO3)2·3H2O | catena(bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-europium hydrate) | triclinic | P1_ | a 6.179 b 8.464 c 12.856, α 105.13° β 90.46° γ 104.86° | [11] | ||||
[Eu(H2O)]2(C2O4)(CO3)2 | [14] | ||||||||
[Gd(H2O)]2(C2O4)(CO3)2 | [14] | ||||||||
[Tb(H2O)]2(C2O4)(CO3)2 | [14] | ||||||||
[Dy(H2O)]2(C2O4)(CO3)2 | [14] | ||||||||
[Ho(H2O)]2(C2O4)(CO3)2 | [14] | ||||||||
Er2(CO3)2(C2O4)(H2O)2 | monoclinic | Cm | a = 7.773, b = 14.920, c = 4.7309, β = 90.12° Z = 2 | [15] | |||||
Pb[ZrО(C2O4)CO3] | |||||||||
Pb4(CO3)2(C2O4)(OH)2 | 535.41 | monoclinic | P21/c | a=11.8593 b=5.2486 c=9.0997 β =96.669 Z=4 | 562.58 | 6.321 | colourless | [16] | |
(NH4)4[Th(CO3)2(C2O4)2]•0.5Н2O | [17] | ||||||||
(NH4)4[Th(CO3)2(C2O4)2]•10Н2O | [17] | ||||||||
(CN3H6)3(NH4)[Th(CO3)2(C2O4)2]•3Н2O | [17] | ||||||||
(CN3H6)3(NH4)[Th(CO3)3(C2O4)]•1.5Н2O | [17] | ||||||||
(CN3H6)3(NH4)[Th(CO3)3(C2O4)]•3Н2O | [17] | ||||||||
(CN3H6)6[Th2(CO3)5(C2O4)] | hexaguandinium pentacarbonatooxalato dithorium | [18] | |||||||
(CN3H6)6[Th2(CO3)5(C2O4)2]•4Н2O | [17] | ||||||||
(CN3H6)6[Th2(CO3)5(C2O4)2]•8Н2O | [17] | ||||||||
(CN3H6)6[Th2(CO3)4(C2O4)3]•14Н2O | [17] | ||||||||
(CN3H6)8[Th2(CO3)7(C2O4)] | [17] | ||||||||
(CN3H6)8[Th2(CO3)7(C2O4)]•5Н2O | [17] | ||||||||
(CN3H6)8[Th2(CO3)7(C2O4)]•6Н2O | [17] | ||||||||
(CN3H6)8[Th2(CO3)5(C2O4)3]•Н2O | [17] | ||||||||
(CN3H6)10[Th2(CO3)8(C2O4)]•8Н2O | [17] | ||||||||
Na4[Th2(OH)2(CO3)4(C2O4)]•4Н2O | [17] | ||||||||
Na4[Th2(OH)6(CO3)2(C2O4)]•2Н2O | [17] | ||||||||
Na8Th(C2O4)2(CO3)4 •11Н2O | [19] | ||||||||
Na8[Th(CO3)5(C2O4)]•11Н2O | [17] | ||||||||
Na10[Th(CO3)5(C2O4)2]•11Н2O | [17] | ||||||||
Na10[Th(CO3)5(C2O4)2]•16Н2O | [17] | ||||||||
Na10[Th(OH)2(CO3)3(C2O4)3]•8Н2O | [17] | ||||||||
Na10[Th(OH)2(CO3)3(C2O4)3] | [17] | ||||||||
Na12[Th(CO3)6(C2O4)2]•11Н2O | [17] | ||||||||
K2[Th2(OH)2(CO3)3(C2O4)]•2Н2O | [17] | ||||||||
K2[Th2(OH)2(CO3)3(C2O4)] | [17] | ||||||||
K4[Th(CO3)3(C2O4)]•6Н2O | [17] | ||||||||
K5[Th2(OH)(CO3)4(C2O4)2]•2Н2O | [17] | ||||||||
K6[Th(CO3)4(C2O4)]•8Н2O | [17] | ||||||||
K6[Th(CO3)3(C2O4)2]•4Н2O | [17] | ||||||||
K6[Th2(CO3)5(C2O4)2]•2Н2O | [17] | ||||||||
K6[Th2(CO3)4(C2O4)3]•6Н2O | [17] | ||||||||
K8[Th2(CO3)5(C2O4)3]•13Н2O | [17] | ||||||||
K8[Th2(CO3)5(C2O4)3]•16Н2O | [17] | ||||||||
K10[Th2(CO3)7(C2O4)2]•8Н2O | [17] | ||||||||
K10[Th2(CO3)7(C2O4)2]•12Н2O | [17] | ||||||||
K10[Th2(CO3)7(C2O4)2]•14Н2O | [17] | ||||||||
K10[Th2(CO3)5(C2O4)4]•5Н2O | [17] | ||||||||
K10[Th2(CO3)5(C2O4)4]•7Н2O | [17] | ||||||||
(NH4)(CN3H6)3[(UO2)2(CO3)(C2O4)2(C3H4N2O2)] · H2O | [20] | ||||||||
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C5H8N2O2)] · 1.5H2O | guanidonium μ-carbonate μ-ethylmethylgyoximatedioxylatediuranylate sesquihydrate | monoclinic | P21 | a=6.909 b=15.794 c=30.064 β=96.720° Z=4 | 3258 | 2.383 | red plates | [20] [21] | |
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H8N2O2)] · 3H2O | [20] | ||||||||
(NH4)(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H4N2O2)] · H2O | [20] | ||||||||
(CN3H6)4[(UO2)2(C6H8N2O2)(CO3)(C2O4)2] · (C6H10N2O2) · 2H2O | guanidinium (3-methyl-1,2-cyclopenadionedioxime)dioxalato (μ-3-methyl-1,2-cyclopenadionedioxato) μ-carbonatodiuranylate dihydrate | triclinic | P1_ | a=9.2474 b=14.8562 c=16.8917 α = 68.504° β = 77.721° γ = 89.792° Z=2 | 2102.7 | 2.108 | red | [22] | |
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C7H10N2O2)] · H2O | [20] | ||||||||
NH4(CN3H6)3[(UO2)2(C7H10N2O2)(CO3)(C2O4)2] · 2H2O | ammonium guanidinium dioxalato (μ-3-methyl-1,2-cyclopenadionedioxato) μ-carbonatodiuranylate dihydrate | orthorhombic | P212121 | a=9.904 b=17.400 c=18.757 Z=4 | 3232.2 | 2.393 | red | [22] | |
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H10N2O2)] · H2O | guanidinium dioxalato μ-diethylglyoximato μ-carbonatodiuranylate monohydrate | 1176.59 | monoclinic | P21/n | a=7.6140 b=15.4388 c=28.010 β=95.99° Z=4 | 3274.6 | 2.387 | orange | [23] |
(CN3H6)2(C2H2N2)[(UO2)2(CO3)(C2O4)2(C6H10N2O2)] · 3H2O | guanidinium ethylenediammonium dioxalato μ-diethylglyoximato μ-carbonatodiuranylate monohydrate | orange | [23] | ||||||
[C(NH2)310[(UO2)6(μ3-O)2(μ2-OH)2(C2O4)4(CO3)4]· 2H2O | 2913.21 | triclinic | P1_ | a=11.5919 b=11.7868 c=13.3545 α = 102.637° β = 93.278° γ = 95.273° Z=1 | 1759.7 | 2.749 | yellow | [24] | |
Pu | Plutonium(III) oxalate carbonate | [25] |
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