Alexander or Alex Walker may refer to:
- Alexander Walker (cricketer) (1842–1903), Scottish cricketer
- Alex Walker (footballer, born 1881) (1881–1916), Scottish footballer
- Alex Walker (footballer, born 1984), Scottish footballer
- Alex Walker (rugby union, born 1984), Australian rugby union player
- Alex Walker (rugby union, born 1986), Welsh rugby union player
- Alex Walker (rugby league) (born 1995), Scotland rugby league player
- Alexander Walker (physiologist) (1779–1852), Scottish physiologist
- Alexander Walker (1837–1889), British businessman
- Alexander Walker II (1869–1950), British businessman
- Alexander Walker (critic) (1930–2003), film critic
- Alexander Walker (conductor) (born 1973), British conductor
- Alexander Walker (MP) (fl.1547), MP for Lichfield
- Alexander Stuart Walker (1826–1896), Justice of the Supreme Court of Texas
- Alex Walker (The Dumping Ground character), character on The Dumping Ground portrayed by Connor Lawson
- Alex Walker, the lead character of Almost Paradise
- Alex Walker, Mayor of Central Hawke's Bay
- Alexander Walker Scott (1800–1883), Australian entomologist
- Alexander Walker Ogilvie (1829–1902), Canadian politician
- Nickeil Alexander-Walker (born 1998), Canadian basketball player
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